The Implications of Arc Transect Studies for Geochemical Mass-Balance Calculations in Subduction Zones
Jeffrey G. Ryan ((813) 974-1598; ryan@chuma.cas.usf.edu; Department of Geology University of South Florida 4202 East Fowler Ave., Tampa, FL 33620
A quantitative description of the geochemical cycle in subduction zone settings depends both on a careful characterization of trench inputs (subducted sediments and altered crust + associated fluids) and on an accurate cataloguing of chemical outputs (fluid releases in the forearc, volcanism at arcs, subduction inputs to back-arc spreading centers). While clear connections have been established between the compositions of subducted sediments and crust and the chemical signatures of arc lavas, moving from these observations to a rigorous subduction zone mass-balance, even for well-characterized tracers , requires additional data.
The patterns of elemental and isotopic variations evident from the study of cross-arc and forearc/arc (/backarc) transects provide key constraints on subduction zone processes and material fluxes:
Abundance and isotopic constraints on the boron cycle during subduction point to removal of a large (>50%) portion of the input budget beneath forearcs, and a shift with depth from sediment s to altered crust as the primary source of slab B. All documented B releases from subducting slabs are isotopically heavy (d11B >s+8), suggesting deep subduction of slabs with low d11B.