"Iron(III)-Chelex Resin Complex as a Prototypical Heterogeneous Catalyst
for Phosphoester Hydrolysis" Catal.
Commun. 2003, 4, 549–553.
Lykourinou-Tibbs, V.; Ercan, A.; Ming, L.-J.
The Fe3+ complex (but not Cu2+ and Zn2+
complexes) of the cross-linked polystyrene Chelex resin is found to be an
efficient and selective catalyst toward phosphodiester hydrolysis.
The hydrolysis of bis-(p-nitrophenyl)phosphate (BNPP) hydrolysis by Fe3+-Chelex
complex exhibits a pre-equilibrium kinetics with a second-order catalytic
proficiency (in terms of rate = k2 [Fe-Chelex][BNPP]) reaching
one million at ambient temperature and pH 9.0.
reprint
in pdf